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The Hand of the King (Jon Arryn)
The Grand Maester: the head adviser on matters of lore and wisdom. (Maester Luwin)
The master of coin: head of the treasury and finances of the kingdom.
The master of laws: overseer of the law and justice for the kingdom.
The master of ships: overseer of the royal navy.
The master of whisperers: the spymaster and the head of intelligence.
The Lord Commander of the Kingsguard: chief bodyguard of the king and adviser in martial matters. (Brynden Tully "Blackfish")